Alkyne-Based Nanostructures on Silver Substrates

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Éditeur :

Springer


Collection :

Springer Theses

Paru le : 2018-11-02

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Description

Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the authors establish protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.

Pages
119 pages
Collection
Springer Theses
Parution
2018-11-02
Marque
Springer
EAN papier
9783030009960
EAN PDF
9783030009977

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
6359 Ko
Prix
94,94 €
EAN EPUB
9783030009977

Informations sur l'ebook
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
5396 Ko
Prix
94,94 €